The manganese and polimetalic sulphures exploration impact in the Gândacu - Suh rzelul Mare mining zone (north-west of Suceava District, north of Eastern Carpathians) on the environment

Liviu Gheorghe POPESCU, Daniela Alexandra POPESCU

Abstract


The mining activity in Iacobeni Cârlibaba area dates
back as far as the XIII-th century, the first documentary certification being before 1241. After 1775 (when Bucovina was annexed like province to the Austrian Empire) Iacobeni Cârlibaba area was scientifically examined by Austrian geologists.
Geologically and structurally, the Gândacu Suh rzelul Mare mining area belongs to the Crystalline Mesozoic Zone of the Eastern Carpathians. The Crystalline Mesozoic Zone is made up of a system of Alpine Nappes, called the Eastern Central Carpathian Nappes
(S ndulescu, 1984). The exploration and geological surveying work was done in the metamorphic basement of the Sub-Bucovinian Nappe.
In the Iacobeni Cârlibaba mining area, the manganese ore deposits are located in the epimetamorphic Tulghe 2 level (Tg2) of Tulghe lithogroup and the polimetalic sulphures ore deposits in the Tulghe 3 level (Tg3). Geographically, the area Gândacu Suh rzelul Mare is situated in the Suhard Mountains, on the right slope of the Golden Bistri a river, from an administrative point of view belonging
to Cârlibaba, Cioc ne ti and partially to Iacobeni. The prospection works outlined three research perimeters: Puiu - Suh rzel, Humoru and Diaca Gândacu. The geological study in the area Puiu Suh rzel showed the presence of polimetalic sulphures ore in acid riolitic metavulcanites, sericite or sericite-chloritic schists. In the same
perimeter, in the superior drainage basin of the Recele brook, its discovered a manganous level in black quartzite with intercalations of sericite-graphitic schists. The manganese ore is predominantly siliceous, made up of lens and nests in parallel disposition. On the left slope of the Suh rzelul Mare brook it uncovered polychrome limestone ores. In the Humoru and Diaca Gândacu perimeters the prospection works highlighted a primary ore of manganese consisting of rhodonite, rhodochrosite, manganese silicates, quarts,
calcite, pyrite, etc. The secondary ore of manganese, resulted from the alteration of the primary ore, appears sporadically and it is made up of manganese and iron oxides and hydroxides. The prospection and research works in the three perimetres ended in the interval 1991-1996.


Keywords


exploration, dump ground, pollution, impact, environment.

Full Text:

PDF

References


Alth A. (1858), Ein Ausflug in die Marmaroscher Karpathen. Mitt. Geogr. Gess., Wien.

B lan M. (1976), Mineralogia z c mintelor manganifere de la Iacobeni. Edit. Academiei

Române, Bucure ti.

B ncil I. (1958), Geologia Carpa ilor Orientali. Edit. tiin ific , Bucure ti, 376 p.

Balintoni I. (2005), Raport de cercetare Grant 6/166, Revista de Politica tiin ei i

Scientometrie, p. 1 - 39, Bucure ti.

Bercia I., Bercia E., Kräutner H., Kräutner F., Mure an M. (1963), Cercet ri stratigrafice

i structurale în regiunea Valea Bistri ei Cioc ne ti Fundul Moldovei (Carpa ii

Orientali). Arh. Com. Stat Geol.

Bercia I., Bercia E., Kräutner H., Kräutner F., Mure an G., Mure an M. (1964), Studiul

microtectonic i stratonomic al isturilor cristaline din zona Cârlibaba. Cercet ri

stratigrafice i structurale în regiunea Cioc ne ti Cârlibaba Bretila (Carpa ii

Orientali). Arh. Com. Stat Geol.

Bercia I., Bercia E. (1970), Contribu ii la cunoa terea geologiei regiunii Vatra Dornei

Iacobeni (Carpa ii Orientali). An. Inst. Geol., 38, p. 7 - 22, Bucure ti.

Bercia I., Bercia E., S ndulescu M., Szasz I. (1975), Harta geologic la scara 1:50 000

foaia Vatra Dornei. Inst. Geol. Rom., Bucure ti.

Bercia I., Kräutner H., Mure an M. (1976), Pre-Mesozoic Metamorphites of the East

Carpathians. An. Inst. Geol. Geofiz., 50, p. 37 - 50, Bucure ti.

Beudant F.S. (1822), Voyage minéralogique en Hongarie pendant lannée 1812. Paris.

Bodin T., Ionescu C. (1955), Raport geologic asupra cercet rilor din regiunea Cârlibaba.

Arh. Com. Stat Geol.

Cotta B. v. (1855), Die Erzlagerstätten der südlichen Bukovina. Jb. d. k. k. geol. R.A., VI, 1,

p. 103 - 134, Wien.

Corbu M. (1954), Raport geologic asupra lucr rilor de explorare din antierul Cârlibaba.

Arh. Com. Stat Geol.

Costeanu N.D., Kokoszinski A. (1928), Contributions à la contributions des minéraux de

Bucovine. Les gisements manganésifères dArchitza. Buletinul Facult ii de tiin e

Cern u i, II, 1.

Dimitrescu R. (1960), Observa iuni privind depozitele mezozoice i tectonica regiunii

Iacobeni. S. S. N. G. Comunic ri de Geol. - Geogr. I (1957 1959), Bucure ti.

Dimitrescu R. (1965), Not asupra cristalinului din regiunea Iacobeni. D. S. Inst. Geol.,

LI/1, p.15 - 22, Bucure ti.

Hauer F. (1859), Geologische Aufnahmen über die untersuchungen der östlichen

Grenzgebirge Siebenbürgens. Jb., k.k. Geol. R.- A., X, Wien.

Hîrtopanu P., Nedelcu L., Moga C., Poda c I. (1997), Structure, lithostratigraphy,

metamorphism and metallogeny of Crystalline Zone of the East Carpathians (Northern

Bistri a Mountains). Rom. J. Mineralogy, 78, p. 26 - 33, Bucharest.

Hîrtopanu P.(1999), Alabandite from metamorphosed Mn deposits from Bistri a Mts

(Romania). Rom. J. Mineralogy, 79, p. 37, Bucharest.

Hîrtopanu P., Cristea C., Stelea G., Nec ulescu D. (1999), Bannisterite in the Tolovanu Mn

deposit, the first occurrence in Romania. Rom. J. Mineralogy, 79, p. 85 - 90,

Bucharest.

Hîrtopanu P., Cristea C. (1999), Manganpyrosmalite in the manganese deposits of the

Bistri a Mts: the first occurrence in Romania. Rom. J. Mineralogy, 79, p. 91 - 95,

Bucharest.

Hîrtopanu P., Popescu M. (1999), Geochemistry and some considerations about origin of the

Bistri a manganese deposits, East Carpathians, Romania. An. Univ. Bucure ti,

XLVIII, p. 32 - 34, Bucure ti.

Hîrtopanu P., Scott P. (1999), Mineralogy and genesis of metamorphic manganese deposits

from Bistri a Mountains, East Carpathians, Romania. Mineral Deposits: Processes to

Processing, Stanley et al. (eds), p. 946 - 950.

Hîrtopanu P. (2000 a), Sulphides of Mn metamorphosed deposits in the Bistri a Mountains,

Romania. Rom. J. Mineralogy, 79, p. 48 - 51, Bucharest.

Hîrtopanu P. (2000 b), Rare minerals in the Carpathians metamorphosed Mn-Fe deposits

from Romania. Acta Mineralogica-Petrographica, XLI, p. 50, Bucharest.

Hîrtopanu P. (2002 a), Influence of the fluid phase composition on the mineral

transformations in Mn metamorphosed ore in Bistri a Mts, East Carpathians. Rom. J.

Mineral. Deposits, 80, p. 88 - 91, Bucharest.

Hîrtopanu P. (2002 b), Johannsenite and its mineral associations from Bistri a Mts, East

Carpathians. 18th General Meeting of the IMA, Edinbourgh, Scotland, Mineralogy for

the New Millenium, Programme with abstracts, p. 273.

Hîrtopanu P. (2003), Mineralogy, origin and metamorphism of Mn-deposits from Bistri a

Mts, East Carpathians. 5th Symposium of GSR, Baia Mare Branch, An. Inst. Geol., 73,

p. 16 - 17, Bucure ti.

Hîrtopanu P. (2004), Mineralogeneza centurii manganifere din Mun ii Bistri ei. Edit. Cartea

Universitar , 352 p., Bucure ti.

Ianovici V. (1956), Informations généraux sur les gisements des minéraux de Mn de la

Roumanie. Symp. Manganese, XX, Congr. Geol. Internat., Mexico, V.

Ianovici V., Dimitriu Al., Ionescu C. (1966), Studiul geologic i geochimic al z c mintelor

de Mn de la Dadu i Co na (Carpa ii Orientali). Stud. cerc. geol. geofiz. geogr.,

Geologie, II/1, 77 p., Bucure ti.

Ianovici V., Dimitriu Al., Ionescu C. (1967), Les caractères distinctifs chimicominéralogiques

des minéraux de manganèse de la R. S. Roumanie. Assoc. geol. carp. -

balk., VIII-éme Congr., Belgrade, Raports, Mineralogie, Geochimie, age absolu, 235.

Ianovici V., Constantinof D., Dr ghici C., Ionescu C., Dimitriu Al. (1968), Mineralogy of

Mn deposits in Romania. XXIII Internat. Geol. Congr., 13, p. 269.

Ionescu C. (1959), Raport asupra cercet rilor geologice i petrografice în regiunea Cîrlibaba

Cioc ne ti Iacobeni. Arh. Com. Stat Geol.

Ionescu C. (1962 a), Cercet ri geologice i petrografice în regiunea Cârlibaba Cioc ne ti

Iacobeni. D. S. Com. Geol., XLVII (1959 1960), Bucure ti.

Ionescu C. (1962 b), Raport geologic privind rezultatele lucr rilor de prospec iuni pentru

sulfuri complexe din regiunea izvoarelor Ceremu ului Cârlibaba Iacobeni - Co na.

Arh. Com. Stat Geol.

Kräutner Th. (1930), Observa iuni geologice în Mun ii Bistri ei i Bârg ului. D. S. Inst.

Geol., XIV (1925 1926), Bucure ti.

Kräutner Th. (1938), Das kristaline Masiv von Rodna (Ostkarpathen). An. Inst. Geol.

Geofiz., 19, Bucure ti.

Kräutner H. (1965), Considera iuni genetice asupra z c mintelor de sulfuri complexe din

cristalinul Carpa ilor Orientali. Acad. R. P. R., Stud. Cercet. Geol., geofiz., geogr.,

Seria Geol., 10, 1, Bucure ti.

Kräutner H.G., Kräutner Fl., T n sescu A., Neac u V. (1976), Interprétation des âges

radiométrique K/Ar pour les roches métamorphiques régénérées. Un exemple - les

Carpates Orientales. An. Inst. Geol. Geofiz., 50, p. 167 - 229, Bucure ti.

Kräutner H.G. (1980), Lithostratigraphic correlation of Precambrian in The Romanian

Carpathians. An. Inst. Geol. Geofiz., 50, p. 167 - 229, Bucure ti.

Lillienbach L. (1834), Journal dun voyage géologique en Bukovine, Transylvanie et dans

Marmarosch. Mém. Soc. Géol, France, I, Paris.

Mastacan G. (1948 a), Beiträge zur Kenntnis der kristallinen Gegend swischen Cioc ne ti

Vatra Dornei. Rev. St. Vasile Adamachi, XXXIV, 3, Ia i.

Mastacan G. (1948 b), La région cristalline du sud-ouest de la Bucovine. Bul. Politehnicii

Gh. Asachi, III, 1, Ia i.

Mastacan G. (1953), Observa iuni geologice i petrografice în regiunea Cioc ne ti

Cârlibaba. D. S. Com. Geol. XXXVII (1949 1950), Bucure ti.

Mastacan M., Bîgu G. (1954), Raport geologic asupra lucr rilor de explorare pentru fier în

regiunea Iacobeni. Arh. Com. Stat Geol.

Mogilnicki R.von (1917), Z c mintele de Mn ale Bucovinei sudice, traducere din limba

german . (Berg. Und Huttenmanischen Jahrbuch).

Munteanu M. (1993), A new occurrence of helvite in Romania, Oi a deposits, Bistri a

Mountains. Rom. J. Mineralogy, 76, 1, p. 127-128, Bucharest.

Nicolau Th. (1920), Le manganite dArchitza. Ann. Sci. Univ. Jassy, X, p. 293 - 295.

Paul K. M. (1876), Grundzüge der Geologie der Bukovina. Jb. d.k.k. geol. R. A., 26.

Perseil E., Vod A. (1995), Les concentrations Fe-manganésifères des Carpates Orientales:

le gisement de Oi a (Roumanie). Bull. Mus. Nat. Hist., Paris, 4/16, p. 383 - 401.

Quiring H. (1922), Die Manganerzvorkkommen in den kristallinen Schiefern der

bukowinischen Waldkarpathen. Arkiv f. Lagerstättenforschung, 30, Berlin.

R dulescu I., R dulescu L., Costache P., Barbu F., Constantinof D. (1960), Raport asupra

prospec iunilor pentru fier în regiunea Cârlibaba Iacobeni esuri Lucina - Bahna.

Arh. Com. Stat Geol.

R dulescu D.P., Ignat V.G. (1958), Neotokit in den Manganerzen von Jakubeny (Rumanien).

N. Jb. Min. Mh., 2/3, p.3 - 9, Stuttgart.

R dulescu D.P. (1962), Contribu ii la cunoa terea mineralelor din z c mintele de mangan

din Moldova de nord. D. S. Inst. Geol., XLIII (1955 - 1956), Bucure ti.

Sandu R. (1960), Contribu ii la studiul oxizilor de mangan. Concentra iile din regiunea

Suceava. Bul. I. P. G. G., VI, Bucure ti.

Savul M. (1948), Raport asupra aflorimentelor de magnetit de la Iacobeni Bucovina. Arh.

Com. Stat Geol.

Savul M. (1949), Raport asupra cercet rilor din regiunea Cârlibaba. Arh. Com. Stat Geol.

Savul M. (1950), Raport asupra regiunii Cârlibaba - Bucovina. Arh. Com. Stat Geol.

Savul M., Mastacan G. (1950 a), Contributions à la connaissance des schistes cristallins de

Bucovina. Les amphibolites de la région Iacobeni Vatra Dornei. Ann. Sci. Univ.

Jassy, Sect. II, XXVI, 2, p. 823 - 835, Ia i.

Savul M., Mastacan G. (1950 b), Raportul cercet rilor f cute pe teren în vara anului 1950

asupra rocilor cu magnetit din regiunea Iacobeni. Arh. Com. Stat Geol.

Savul M., Mastacan G. (1952 a), Contribu ii la cunoa terea gnaiselor porfiroide din

Carpa ii Orientali. Acad. R. P. R. Bul. t. Biol.- Geol.- Geogr., IV, 2, Bucure ti.

Savul M., Mastacan G. (1952 b), Rocile cu magnetit de la Iacobeni (regiunea Suceava). D.

S. Com. Geol. XLII (1951), p. 611 - 618, Bucure ti.

Savul M., Ianovici V. (1957), Chimismul i originea rocilor cu mangan din cristalinul

Bistri ei. Bul. t., Geol. Geogr., II, 1, p. 119 - 136.

Savul M., Ianovici V. (1958), Chimismul rocilor cu mangan din Carpa ii Orientali i

Meridionali din R.P.R. Stud. cerc. geol. geofiz. geogr., Geologie, III/1-2, Bucure ti.

S ndulescu M. (1984), Geotectonica României. Edit. Tehnic , 336 p., Bucure ti.

Slavik Fr. (1929), Note sur lanthophyllite asbeste manganifère des mines de Jacobeni

Ar i a. Ann. Sci. Univ. Jassy, XV, p. 13 - 19.

Vod A., Munteanu M. (1996), Lithostratigraphic, structural and metallogenetic

correlations in the East Carpathians Crystalline-Mesozoic Zone. An. Inst. Geol. Rom.,

/1, p. 265 - 267, Bucure ti.

Vod Al., Balintoni I. (1994), Corel ri stratigrafice în cristalinul Carpa ilor Orientali.

Studia Univ. Babe Bolyai, Geologia, 39 (1-2), p .61 - 66, Cluj Napoca.

Walter B. (1876), Die Erzlagerstätten der südlichen Bukowina. Jb. d. k. k. geol. R.A., 26, V,

I, p. 343 - 426, Wien.

*** Arhiva S.C.GEOMOLD S.A. Câmpulung Moldovenesc.

*** Arhiva S.C. MINBUCOVINA S.A. Vatra Dornei.